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The METS remediation
process equipment is about the size of a large van.
It is fully mobile and self-propelled. Previously
excavated soil is deposited in the hopper at the top
of the apparatus by a conventional front-end loader.
Very large debris, such as rock, concrete or asphalt,
is usually screened off at the hopper opening. From
the hopper, the soil is transferred in a regulated
flow to a custom designed processing mill. The mill
impacts and shreds the soil, while blending a treatment
solution (chemical, biological, or both), along with
air and moisture, into the soil using a patented process.
The contaminant molecules in the soil are already
being degraded or neutralised by the time the soil
emerges from the processing mill. The treated soil
may be deposited directly to the ground from the mill.
However, the apparatus includes a conveyor system
at the back end, which may be used to deposit the
soil in locations and configurations as desired or
to meet site space constraints.
Technical Principles
The METS process is designed to meet all of the critical
requirements for a successful soil remediation technology
(i.e., one that produces "non-detect" results
from today's standard soil testing methods, consistently
and quickly), which are:
- Ability to apply a wide variety
of proven chemical and biological remediation treatment
products that are available today, as well as those
yet to be invented.
Virtually any contaminant is susceptible to
being degraded or neutralised at the molecular level
by a chemical reaction or digestion by microbes.
A great deal of research and development has gone
on, and continues to go on, with the objective of
finding or creating specific treatment products
based on this principle. It is not as widely known
that such products have already been created and,
in some cases, are already in commercial use. For
reasons that will be explained shortly, these products
have not been used reliably or extensively for remediation
of contaminated soil, prior to the commercialisation
of METS.
An example of such a commercially
available product (as described in its patent:
P/N 5,478,389) is a composition of a soluble silicate
(in this case, sodium silicate), an anionic surfactant
(an ester of organo-phosphoric acid), and a polyol
(ethylene glycol), among other ingredients. The
product is used most commonly today to degrade
hydrocarbons as part of various cleaning and degreasing
applications (for example, in maintenance or emergency
spill treatment activities at oil refineries).
The details of the chemical reactions involved
are proprietary and confidential, but the reactions
are complex and, to a large extent, occur simultaneously.
The reactions begin immediately upon application,
quickly enough to inhibit the volatilization of
any toxic components into the atmosphere before
the degradation process is completed. We have
found that this product, when modified for our
process, works as effectively in degrading hydrocarbon
contamination in soil as it does in the cleaning
or degreasing applications.
Another example of products based
on a chemical reaction strategy is a practical
implementation of a well-understood chemical principle
known as Fenton's Reagent Chemistry. FRC provides
for direct oxidation -- release of nascent oxygen
-- via an exothermic reaction between a peroxide
and a catalyst. The exothermic reaction as well
as oxygen release, dependent upon catalyst, degrades
the hydrocarbon molecule to its carbon and hydrogen
elements. The nascent oxygen reacts with these
elements to form benign compounds (for example,
in the case of gasoline, the by-products are water
and carbon dioxide). Chemical reactions based
on this chemistry are reliable and predictable,
once the proper environment has been created.
Researchers in a variety of organisations
and enterprises have identified and cultured microbes
that are proven to degrade and/or neutralize various
types of contaminants. In all known cases, these
are naturally occurring biological organisms that
have been found to thrive in environments where
these contaminants have been introduced by man-made
events or by natural causes. Not all of these
discoveries have led to commercially available
products, but we have been cataloguing them for
compatibility with our process, and are confident
that we will have no problem obtaining practical
access to such "products" even if they
are not yet on the open commercial market.
In short, the means to degrade,
destroy and/or permanently neutralise contaminant
compounds exists today. We do not believe that
there is any form of contamination that is forever
immune to chemical and/or biological treatment.
- Inconsistencies in soil conditions
and content require excavation and proper processing
to create a consistent and predictable soil matrix.
The primary reason that the products described above
have not been widely used to remediate contaminated
soil is the lack of an effective, reliable and versatile
method for introducing reagents into a stock of
soil. Soil conditions found in nature can vary significantly
within a matter of a few feet, or even a few inches
(vertically and horizontally). Soil naturally varies
in its composition (e.g., clay, sand, hardcore,
gravel, etc.), compaction, acidity, moisture content,
etc. Moreover, a stock of soil can contain a variety
of materials such as rock, wood, metal debris, etc.,
which are capable of obstructing the free flow of
air and moisture.
Nevertheless, most of those who
have been developing and promoting soil remediation
technologies, from vapour extraction, sparging,
bio-injection, thermal treatment, soil-washing,
etc., have operated on the assumption that this
variability is not a significant constraint on
the effectiveness and efficiency of such technologies.
Yet these technologies have not been effective
in removing or neutralizing contamination, except
under controlled conditions, or with incomplete
results, or through intervention with highly expensive
and/or slow acting processes. In fact, in our
view, the only credible and meaningful success
stories associated with these technologies (especially
bioremediation) is where they have been applied
to create barriers in front of contaminant plumes.
We have determined, after several
years of research and practical experience with
a variety of these technologies, that this variability
of soil conditions and content is the principal,
if not sole, barrier to effective and efficient
remediation of contamination-saturated soil. We
believe that for any remediation technology to
be considered viable it must, first and foremost,
have a means of eliminating this variability in
the soil, in conjunction with introducing one
or more chemical/ biological reagent(s). Second,
the method for rendering the soil into a homogenous
matrix must reduce the soil to a fine particle
state in order to maximize access to the contaminant
molecules. Third, the method must have a means
of ensuring that the reagent(s) is evenly distributed
throughout this homogenous soil matrix, and allowed
to complete the degradation/neutralization process,
before the soil loses its homogenous and fine
particulate composition.
Finally, to promote speed and
efficiency, the soil matrix should include, at
least initially, a relatively high level of air
entrainment and a carefully calibrated level of
moisture content. These are efficacious conditions
for promoting and sustaining the desired chemical
reactions; they are even more critical for a treatment
regime based on biological organisms. We have
found for example, that bioremediation methods
that do not create these conditions (homogenous
matrix, fine particulate, effective distribution,
air entrainment and proper moisture) can take
many months to show meaningful results, and may
take years to achieve remediation objectives (perhaps
requiring periodic re-injections of the biological
reagents). However, with our process, meaningful
results using biological organisms can be seen
within hours, and remediation objectives achieved
within a few weeks.
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Adaptation of existing soil
processing technology to create a homogenous,
fine particle soil matrix.
Knowing that successful remediation
technologies would depend upon effective soil
processing technologies -- i.e., technologies
that (1) create a homogenous soil matrix consisting
of fine particle soil elements; (2) ensure even
distribution of chemical/biological reagents;
(3) promote air entrainment; and so forth -- we
began researching and evaluating possible candidates.
We did not consider inventing such a technology
because we did not believe it would be necessary
to do so. In addition, we did not want our process
design to be hampered by uncertainties about the
performance of such a critical element.
We did not find such candidates
in the environmental remediation industry. We
did, however, find many attractive candidates,
presenting various combinations of strengths and
weaknesses for our purposes, in the mining, sand-and-gravel
and agricultural equipment industries. Processing
and treatment of soils and soil content is, of
course, a vital element in mining and sand-and-gravel
operations, and in agriculture. In addition, we
found similar technologies starting to become
more common in the demolition industry (for materials
processing) and some other industries far removed
from, or at least outside the understanding of,
the environmental remediation industry.
It does not serve the purposes
of this paper to detail this part of our investigation.
It should be sufficient to say that we not only
researched these technologies, but also in certain
instances made practical application of them to
the purpose of remediating contaminated soil or
simulations thereof. As a result, we were able
to identify the best technology, its commercial
embodiments and the basis for modifying it to
meet our objectives.
It should be noted, in the interest
of proper disclosure, that we are not the only
company or inventor who has identified the need
for or usefulness of soil processing equipment,
of one type or another, to environmental remediation.
We know of others who have attempted to commercialize
inventions based on this insight, and we are also
familiar with a variety of patents that have been
issued, which contain references to the use of
such equipment for environmental remediation.
We do not, however, know of any other company
or inventor who has succeeded in developing a
practical and commercially proven process that
meets all of the criteria for success that we
identified especially the ability and knowledge
base necessary to remediate a wide range of contaminant
types in a wide range of soil conditions, with
efficiency and reliability.
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Proper integration of chemical/biological
treatment reagents with the soil processing mechanism.
As noted above, it is a necessary
but not sufficient condition for success that
the soil be processed into a homogenous matrix
of fine particle soil elements. In addition, there
has to be a means for evenly distributing the
chemical/biological reagent(s) throughout the
soil while it is in this homogenous state. In
order to meet this objective, we again conducted
research into commercially available technologies
that could be adapted to the purpose. We were
able to identify a number of promising candidates,
primarily in the agricultural equipment industry.
In this industry, of course, it is desirable to
obtain even distributions of chemicals, nutrients,
and organic materials, into soil. The modifications
required for our purposes were minor and involved
minimal invention on our part.
It is worth noting that a key
principle of our design is also what differentiates
our process to a critical degree from other attempts
at superficially similar remediation technology
inventions. That is, our process distributes the
reagents precisely at the point that the soil
is entering the processing mechanism that produces
the homogenous matrix. As a result, the reagents
are being distributed throughout the contaminated
soil at the exact moment that they are activated
for the degradation/neutralization process. In
addition, this is also the optimal stage for air
entrainment and moisture control. Other remediation
inventions have attempted to introduce the reagents
some substantial time before or after the soil
has been processed and, as a result, achieved
inconsistent or unreliable results, including
having to re-treat the soil. In our system, the
reagent(s) is already in the process of degrading/neutralizing
the contaminant molecules the moment that the
soil exits the processing equipment
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Ability to treat multiple contaminant
types at the same time.
Many remediation projects, particularly
on industrial or military property, are hampered,
if not completely stymied, by the fact that the
soil is contaminated by more than one pollutant/hazardous
material. For example, a stock of soil might be
contaminated with gasoline and soluble lead. All
of the problems and challenges, that make remediating
a single contaminant type so difficult and unreliable,
are compounded when multiple contaminants are
present (in fact, most other remediation technologies
would be hard-pressed to efficiently remediate
soil contaminated with even two different hydrocarbon
types, such as gasoline and motor oil).
The ability to treat soil containing
multiple contaminant types in the same reliable,
efficient, affordable process was not a critical
objective of our research and development effort.
However, we quickly discovered that the technologies
we identified, and the processes we designed,
were easily and readily adaptable to treating
multiple contaminant types during a single pass
through the process equipment. In fact, the modifications
required to achieve this result are trivial. Essentially,
they involve installing a series of separate storage
and distribution systems acting in parallel, each
of which applies a different reagent to the soil
(for example, one reagent to degrade the diesel
fuel, another reagent to neutralize the soluble
lead) at the same time. There is no practical
limit to the number of reagent delivery systems
involved, and therefore number of contaminant
types that may be treated in this way, other than
constraints on the desired physical size of the
processing equipment.
On the other hand, we recognize
the possibility that, in certain circumstance,
activities by one reagent may hamper or block
the actions by another (for example, a chemical
reagent might be harmful to, or inhibit a biological
organism until the chemical reactions are completed).
Those situations, which we think will be rare,
would be identified in laboratory testing prior
to field application. In that event, the simple
solution would be the run the soil through the
process equipment a second time.
Conclusion
METS is a commercial reality today. The explanation
of the METS process may seem surprisingly simple to
those who have been frustrated by the failure of other
remediation technologies. The trend in recent years
has been to adopt remediation technologies that contain
a high degree of engineering complexity and expensive,
custom-designed components. Nevertheless, the simplicity
of the technical concepts underlying the design of
the METS process is part of the reason why it is so
powerful. This is also why METS is the only fully
commercial technology, existing today, that can treat
such a wide range of contamination problems faster
and at a lower cost than any other active method of
remediation, including land filling (i.e., "dig,
haul and dump")
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